What is in the yellow section

In the 2024 edition the yellow section runs from printed page 29 to page 86 and holds 2,771 rows for 1,983 different ID numbers. Each row is an ID number, a guide number and a name of material. 522 rows are highlighted in green, which means the material also has a row in Table 1. The 62 guides the numbers point to are in the orange section.

One number can have many rows. ID 1075, for example, appears 9 times, as Butane, Butylene, Isobutane, Isobutylene, Liquefied petroleum gas, LPG, Petroleum gases, liquefied, Propane, Propylene, all with Guide 115. Scan every row for your number before you move on, because a name can change whether the row is green.

Worked example: the number beats the placard

A cargo tank shows a class 3 placard with 1203 across the middle. The placard alone would point to Guide 127 in the placard table. The yellow section, page 32, says 1203 is Gasoline, Guide 128, not highlighted. So the guide is 128, and the first distance is its immediate precautionary measure: Guide 128's immediate precautionary measure: isolate at least 50 m in all directions. Entering 127 in the drill gets this feedback: "127 is the placard table's guide for this placard. With an ID number, use the yellow index instead: 1203 is Guide 128."

The P after a guide number

Some rows print a P after the guide, as 1040 Ethylene oxide does with Guide 119P. The P warns that the material may polymerize violently, for example when heated or contaminated. The guide page itself is the number without the P. In the drill, a guide typed without its P is still right, with the note: "The index prints 119P. The P warns that the material may polymerize violently; the guide page is still 119."

IDs with more than one guide

Almost every ID number maps to a single guide, but not all. In this edition 4 ID numbers send different names to different guides: 1057 (Guides 115, 128); 3166 (Guides 115, 128); 3171 (Guides 138, 147, 154); 3536 (Guides 138, 147). For these the name decides the guide, so read the whole row. Placardset's timed lookup run leaves them out, because it shows only the number.

Where the numbers come from

The ID number, the proper shipping name and the hazard class all come from the regulations' hazardous materials table, and they appear together on the shipping paper. The guidebook adds the guide number and the green highlight. Placardset's drill set takes its classes from that table and its guides from the yellow section, and a test checks that each name is printed in the index with the same guide.

Common mistakes

Check any number with the UN number lookup, or race the clock in the timed lookup run.

Sources

Checked on 27 September 2026. Everything here is said in our own words; the guidebook's text is paraphrased, never quoted at length. Where your instructor, your employer's plan or the current printed guidebook says something different, follow them.

Frequently asked questions

What is the difference between a UN number and an NA number?

Both are four digit ID numbers. UN numbers are international; NA numbers are North American numbers for materials that have no UN number, and the guidebook lists both in the same yellow section.

Why does one ID number have several names?

One number often covers a family of materials or several names for the same one, so the index repeats the number once per name. They usually share one guide.

Is the guide number a page number?

No. Guides are numbered 111 to 174 and each takes two pages in the orange section. Find the guide by its number printed at the top corner of the page.

Can I trust a guide number from memory?

Look it up every time. Several common materials sit next to each other in the index with different guides, and the drill is built to train the lookup, not memory.